A convenient synthesis of 3-(diethoxymethyl)alkanals.
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概要
- 論文の詳細を見る
3-(Diethoxymethyl)alkanals were obtained in moderate yields by the diisobutylaluminium hydride reduction of ethyl 3-(diethcxymethyl)alkanoates, which were simply synthesized in one pot by the copper (II)-catalyzed reaction of ethyl diazoacetate with 1-trimethylsiloxy-1-alkenes, followed by the ring cleavage of the resulting cyclopropanes with concentrated sulfuric acid in the presence of triethyl orthoformate.
- 公益社団法人 日本化学会の論文
著者
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Saigo Kazuhiko
Department Of Chemistry And Biotechnology Faculty Of Engineering The University Of Tokyo
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Nohira Hiroyuki
Department Of Applied Chemistry Faculty Of Engineering Saitama University
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Okagawa Shuji
Department of Applied Chemistry, Faculty of Engineering, Saitama University
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