cis-2-Amino-3, 3-dimethyl-1-indanol : Application as a Highly Efficient Chiral Auxiliary for the Diels-Alder Reaction

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概要

• 論文の詳細を見る

著者

• SAIGO Kazuhiko

  Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo

• Saigo K

  Univ. Tokyo Tokyo Jpn

• Saigo Kazuhiko

  Department Of Chemistry And Biotechnology Faculty Of Engineering The University Of Tokyo

• SUDO Atsushi

  Department of Chemistry and Biotechnology, Faculty of Engineering, The University of Tokyo

• Sudo A

  Department Of Chemistry And Biotechnology Graduate School Of Engineering The University Of Tokyo

• Sudo Atsushi

  Department Of Chemistry And Biotechnology Faculty Of Engineering The University Of Tokyo

• Saigo Kazuhiko

  Department of Applied Chemistry, Faculty of Engineering Saitama University

関連論文

• Topochemical Photopolymerization of 4-[2-(Unsubstituted and Methyl-Substituted Pyrazinyl)ethenyl]cinnamates and -thiocinnamates in the Crystalline State
• Chemical Modification of Amide-Based Catenanes and Rotaxanes II. Synthesis of tertiary Amine [2]Catenanes and [2] Rotaxanes via N-Methylation Followed by Borane Reduction of Secondary Amide [2] Catenanes and [2] Rotaxanes and Mobility of Their Components
• Synthesis and Structure of [2]Catenated tertiary Octamide and Octamine
• Enantiopure trans- and cis-3-Aminoindan-1-ols : Preparation and Application as Novel Basic Resolving Agents
• Highly Regioselective Pinacol Rearrangement of Sulfenylmethylated Glycols
• The Cationic Diels-Alder Reaction, Facile Formation of Cationic Species from 2-Oxoalkyl Esters
• Regio-and Stereoselective Synthesis of a trans-4-[60]Fullerenobisacetic Acid Derivative by a Tether-Directed Biscyclopropanation: A Diacid Component Applicable for the Synthesis of Regio- and Stereo-Regular [60]Fullerene Pearl-Necklace Polyamides
• Formation of Ketones from Alkyl Nitrites in the Solid State
• Diastereoselective Synthesis of cis-4,5-Substituted δ-Lactones by the Reaction of 2-Methoxy-2-(trimethylsiloxy)cyclobutanecarboxylic Esters with Carbonyl Compounds
• Stereoselective Addition Reaction of Organolithium Reagents to Chiral Imines Derived from erythro-2-Amino-1,2-diphenylethanol
• Diastereoselective Synthesis of β-Amino Esters by the Lewis Acid-Mediated Reaction of N-Tosyl Aldimines with Ketane Bis(trimethylsilyl) Acetals
• Photochemical EZ-Isomerization of α,β-Unsaturated Amides and Thioamides in the Solid State
• Novel Copolyamides Containing [60]Fullerene in the Main Chain
• Synthesis and properties of macrocyclic 1,1’-biarenol derivatives prepared by the tandem Claisen rearrangement
• Synthesis of Bis(2-hydroxynaphthamide)Derivatives Behaving as a Fluorophore for Anions
• Unusual Demethylation of O,O'-Dimethyl Chlorothiophosphate with Aryllithiums
• Synthesis and chiral recognition ability of O-phenyl ethylphosphonothioic acid with a conformationally flexible phenoxy group for CH/π interaction
• Synthesis and properties of a diastereopure ionic liquid with planar chirality
• Synthesis of enantiopure 1-substituted, 1,2-disubstituted, and 1,4,5-trisubstituted imidazoles from 1,2-amino alcohols
• Regio- and diastereo-controlled synthesis of bis(formylmethano)[60]fullerenes and their application to the formation of [60]fullerene pearl-necklace polyimines
• Synthesis of Chiral Oligopeptides Which Recognize Double-Stranded DNAs
• Solid-phase Synthesis of a Novel Polyester Analog of Nucleic Acids Bearing a Serine Backbone Using a Linker which Cleaved under Neutral Conditions
• Preparation and identification of bis(formylmethano)[60]fullerene isomers: The first systematic study on bifunctionalized [60]fullerenes with dissymmetric addends
• Regio/diastereo-controls of the Bingel-type biscyclopropanation of [60]fullerene by using bismalonates with a Tröger base analogue-derived tether
• Planar-Chiral Ionic Liquids. Cyclophane-Type Imidazolium Salts with a C(2)-C(4) Bridge
• Design and synthesis of novel imidazolium-based ionic liquids with a pseudo crown-ether moiety: diastereomeric interaction of a racemic ionic liquid with enantiopure europium complexes
• Synthesis of Chiral Oligopeptides Which Recognize Double-Stranded DNAs
• Solid-Phase Synthesis of a Novel Polyester Analog of Nucleic Acid Bearing Serine Backbone
• cis-2-Amino-3, 3-dimethyl-1-indanol : Application as a Highly Efficient Chiral Auxiliary for the Diels-Alder Reaction
• α-Sulfenyl-Directed Ring-Opening Reactions of Epoxides. 1. Highly Regio- and Stereoselective Reaction with Organo-Aluminum Reagents and Application to the Synthesis of an Aggregation Pheromone
• Synthesis of Novel Chiral Diamino Acid-based Polyamide as Analogues of Nucleic Acids
• Characterization of Plasmodium falciparum calcium-dependent protein kinase 4
• Optical resolution of 2-amino-1,2-diphenylethanol by preferential crystallization and its utilization in fractional crystallization and enantioselective reduction of prochiral ketones.
• Improved optical resolution of (.+-.)-1,2-diphenylethylenediamine.
• Synthesis of dichlorocyclobuta[b]benzofuran-2a-carboxylic derivatives and 3-(trichloroethenyl)coumarin through cross photocycloadduct of coumarin and tetrachloroethylene.
• Optically active anti head-to-head coumarin dimer. Resolution, absolute configuration, and molecular structure.
• A convenient synthesis of 3-(diethoxymethyl)alkanals.
• A novel chiral stationary phase for optical resolution of amino acids and their derivatives by ligand-exchange high-performance liquid chromatography.
• Molecular dynamics calculation for the complexes of a macrotricyclic receptor with organic substrates.
• Optical resolution of erythro-2-amino-1,2-diphenylethanol by reciprocal crystallization of the diastereomeric salts with (-)-mandelic acid on alternate seeding.
• Optically active anti head-to-head coumarin dimer. A new agent for the determination of enantiomeric excess of amines and alcohols.
• Optical resolution of 2-(anilinomethyl)pyrrolidine.
• Optically active polyamides having (-)-anti head-to-head coumarin dimer component. 2. Chiroptical property in the film state.
• Synthesis of 1,10-disubstituted 1,4,7,10,13,16-hexaazacyclooctadecanes and their extractability for metal cations.
• Reaction of 1,1,2,2-tetrachloro-2,2a.ALPHA.,4.ALPHA.,8b.ALPHA.-tetrahydrocyclobuta-[c]quinolin-3(1H)-one with nucleophiles; Reaction, product structure, and mechanism.
• Molecular recognition in the formation of conglomerate crystal. 2. The role of arenesulfonic acid in the conglomerate crystals of amino acid salts.
• Optically active polyamides having (-)-anti head-to-head coumarin dimer component. 3. Chiral recognition ability.
• Solvent- and wavelength-dependence of the photocleavage of the cyclobutane ring in N,N'-dibutyl-c-3,c-4-bis-(2-hydroxyphenyl)-r-1,c-2-cyclobutanedicarboxamide.

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