Synthesis and properties of macrocyclic 1,1’-biarenol derivatives prepared by the tandem Claisen rearrangement
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概要
- 論文の詳細を見る
Crown ether-type macrocycles consisting of an enantiopure biarenol derivative and an oligoethylene glycol were synthesized by the lewis acid-mediated tandem Claisen rearrangement. This is the first example of the successful application of the tandem Claisen rearrangement to the synthesis of enantiopure macrocyclic biarenol derivatives. The enantiopure macrocyclic biarenols were found to form 1:1 complexes with amino acid salts and to discriminate their chirality.
- Elsevierの論文
- 2005-05-30
著者
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Saigo K
Univ. Tokyo Tokyo Jpn
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Yoshida H
Division Of Environmental Research Ecotopia Science Institute Nagoya University
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