Ortho-selective alkylation of phenols with symmetric sulfides and sulfuryl chloride.
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概要
- 論文の詳細を見る
Sulfuryl chloride has been shown to be useful activator for sulfides in the selective preparation of ortho-alkylated phenols via [2,3]sigmatropic rearrangement. By this process, ortho-alkylated phenols have been prepared with various symmetric sulfides in good yields. The rearrangement products having 3-chloropropyl or 3-methyl-3-butenyl moiety have been converted into 2<I>H</I>-1-benzopyran derivatives.
- 公益社団法人 日本化学会の論文
著者
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Sato Kikumasa
Department Of Applied Chemistry Faculty Of Engineering Yokohama National University
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Miyamoto Osamu
Department Of Neurobiology Faculty Of Medicine Kagawa University
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Inoue Seiichi
Department Of Applied Chemistry Faculty Of Engineering Yokohama National University
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Ota Tomomi
Department Of Applied Chemistry Faculty Of Engineering Yokohama National University
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IKEDA HIROSHI
Deparment of Biology, Faculty of Science, Tokyo Metropolitan University
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