Highly stereoselective synthesis of two natural olefinic diols via N-oxide (2,3)signatropic rearrangement.

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概要

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• The [2,3]sigmatropic rearrangement of α-substituted <I>N</I>,<I>N</I>-dimethylmethallylamine <I>N</I>-oxides results in a highly stereoselective formation of trans olefins oxygenating at the allylic position, and providing a quite efficient synthesis of cuspidiol and plaunotol.

• 公益社団法人 日本化学会の論文

著者

• Sato Kikumasa

  Department Of Applied Chemistry Faculty Of Engineering Yokohama National University

• Honda Kiyoshi

  Department Of Synthetic Chemistry Faculty Of Engineering Yokohama National University

• Inoue Seiichi

  Department Of Applied Chemistry Faculty Of Engineering Yokohama National University

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