Electrogenerated acid-catalyzed Michael reaction of enol silyl ethers and ketene silyl acetals to .ALPHA.,.BETA.-unsaturated carbonyl compounds.
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概要
- 論文の詳細を見る
1,5-Dicarbonyl compounds and their enol silyl ethers were prepared by the reaction of α,β-unsaturated ketones and enol silyl ethers or ketene silyl acetals by using an electrogenerated acid (EG acid) as a catalyst. Similar reaction of 1-trimethylsiloxy-1,3-butadiene with enones produced six-membered adducts as the result of a double-Michael process.
- 公益社団法人 日本化学会の論文
著者
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Torii Sigeru
Department Of Applied Chemistry Faculty Of Engineering Okayama University
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Kurokawa Yuji
Department Of Biotechnology Graduate School Of Engineering
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Inokuchi Tsutomu
Department Of Applied Chemistry Faculty Of Engineering Okayama University
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Takagishi Sadahito
Department of Industrial Chemistry, School of Engineering, Okayama University
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Tanigawa Shinichi
Department of Applied Chemistry, Faculty of Engineering, Okayama University
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Kusumoto Masahiko
Department of Applied Chemistry, Faculty of Engineering, Okayama University
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Kurokawa Yuji
Department of Applied Chemistry, Faculty of Engineering, Okayama University
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Takagishi Sadahito
Department of Applied Chemistry, Faculty of Engineering, Okayama University
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