Removal of α-Hydroxy Group of Acyloins and Their Derivatives with Vanadium(II) - THF Complex
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概要
- 論文の詳細を見る
- 1992-10-05
著者
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Torii Sigeru
Department Of Applied Chemistry Faculty Of Engineering Okayama University
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Inokuchi Tsutomu
Department Of Applied Chemistry Faculty Of Engineering Okayama University
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Inokuchi T
Okayama Univ. Okayama
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KAWAFUCHI Hiroyuki
Toyama National College of Technology
関連論文
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- Synthesis of 3-Chloro-Δ^3-cephem-4-carboxylate by Addition/Cyclization of Allenecarboxylate. Copper(II)-Promoted Aerobic Oxidation of Arenesulfinic Acids
- Aerobic Oxidation of 3-Iodomethyl-Δ^3-cephem-4-carboxylate to 3-Formyl-Δ^3-cephem-4-carboxylate through 3-Hydroperoxymethyl-Δ^3-cephem-4-carboxylate
- Synthesis of dl-Shikonin by Vanadium(II)-Assisted Cross-Coupling and Electrooxidation of Aromatic Nuclei
- Oxidations of Dihydroxyalkanoates to Vicinal Tricarbonyl Compounds with a 4-BzoTENPO-Sodium Bromite System or by Indirect Electrolysis Using 4-BzoTEMPO and Bromide Ion
- Diastereoselective Michael Addition of Magnesium Amide to O-(2-Alkenoyl)TEMPOs and Comparison of Reactivity with Acyl Substituent-Modified Carboxylic Analogues
- Removal of α-Hydroxy Group of Acyloins and Their Derivatives with Vanadium(II) - THF Complex
- Conversion of Cephem into Penam/Penem through Sequential Ring-opening/Recyclization in an Il/BiCl_3/AlCl_3 System
- Synthesis of 2-exo-Methylenepenam by Reductive 1,2-Elimination and S-S Bond Fission in a PbBr_2/Al Bimetal System
- Synthesis of 3-Hydroxycephems from Penicillin G through Cyclization of Chlorinated 4-(phenylsulfonylthio)-2-azetidinones Promoted by a BiCl_3/Sn or TiCl_4/Sn Bimetal Redox
- A Versatile Cycloaddition for the Generation of Pyrrolidine Derivatives vis C-N-C 1, 3-Dipoles
- Electrochemical Wacker Type Reaction with a Double Mediatory System Consisting of Palladium Complex and Tri(4-bromophenyl)amine
- A Novel Ru(VII)/Ru(IV) Mediatory System for Electrooxidation of Primary and Secondary Alcohols, Leading to Aldehydes and Ketones
- Electrochemical Os-Catalyzed Asymmetric Dihydroxylation of Olefins with Sharpless' Ligand
- A synthesis of (.+-.)-.BETA.-vetivone and its related spirovetivanes via the base-catalyzed spiroannelation of phenolic tosylates.
- Tin-promoted electrochemical hydrodimerization of ionones.
- Electrogenerated acid-catalyzed Michael reaction of enol silyl ethers and ketene silyl acetals to .ALPHA.,.BETA.-unsaturated carbonyl compounds.
- Electrogenerated acid-assisted preparation of ethers from aldehydes and ketones.
- Electrogenerated acid-catalyzed reactions of acetals, aldehydes, and ketones with organosilicon compounds, leading to aldol reactions, allylations, cyanations, and hydride additions.
- A straightforward access to 5-deoxy-D-arabinono-1,4-lactone, a versatile intermediate in the lauraceae lactones syntheses.
- Electrogenerated acid as an efficient catalyst for the protection and deprotection of alcohols with dihydropyran and transesterification of glyceride.
- A new oxidizing system for aromatic alcohols by the combination of N-oxoammonium salt and electrosynthesized tetraalkylammonium tribromide.
- Indirect electrooxidation of halohydrins by a double mediatory system of Ru(VIII)/Ru(IV) and (Cl+)/Cl-. Optimization for the oxidation of 1,3-dichloro-2-propanol to 1,3-dichloroacetone.
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- The cross-aldol reaction of 3-alkoxy-2-cyclohexen-1-ones with .ALPHA.,.BETA.-enals. A synthesis of 4-(trans-2-butenylidene)-3,5,5-trimethyl-2-cyclohexen-1-ones.
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- Indicrect electrooxidation by using ruthenium tetraoxide and chloride ion as recycling mediators. Optimization for the oxidation of diisopropylidene-D-glucose to the ulose.
- A novel approach to cis-jasmone and dihydrojasmone from 2-(2-benzothiazolythio)-2-(3-oxobutyl)oct-5-en(or -an)oic acid by electrolytic procedure.
- Anodic Reaction of 5-Alkyl-2-furoic Acids in Protic Solvents
- A convenient synthesis of .ALPHA.-(2-benzothiazolylthio)alkanoates by cleavage of .BETA.-keto esters with 2-benzothiazolesulfenamides.
- A facile synthesis of 3-hydroxymethyl- and 3-formylindoles from o-nitrotoluene.
- Electrogenerated acid-catalyzed cyclization of isoprenoids.
- Formation and Properties of Phenylthiomethyl Radical. Anodic Oxidation of Sodium Phenylthioacetate and Thermal Decomposition of t-Butyl Phenylthioperacetate
- A facile reductive removal of bromine atom(s) of 6,6-dibromo- and 6-bromopenicillanate derivatives in a Pb/Al bimetal system.
- Electrosynthesis of 2-methyl-1,4-naphthoquinone (vitamin K3) directly from 2-methyl-5,8-dihydro-1,4-naphthalenediol by a four-electron oxidation procedure.
- Alicyclic terpenoids from cyclocitryl phenyl sulfides. VI. Syntheses of .BETA.-ionone derivatives.
- Syntheses of 4-(4-hydroxy-2,6-dimethylphenyl)-1,2-butanediol and 4-(4-hydroxy-2,6-dimethylphenyl)-2-butanol.
- cis-2-Pentenyl moiety from 5,6-dihydro-2H-thiopyran. A convenient synthesis of cis-jasmone.
- Annulation of 2H-Pyran onto 1-Oxa- or 1-Azacyclohexane-2,4-diones and Their Analogues via Sequential Condensation with α-Substituted Enals and 6π-Electrocyclization