Simple Preparation of (2,2'-Biphenylylene)phenylphosphine Oxide and Role of Triphenylphosphine Oxide as a Mediator for Formation of Biaryl Derivatives.

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概要

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• (2,2′-Biphenylylene)phenylphosphine oxide (<B>3</B>) was prepared simply by the reaction of triphenylphosphine oxide (<B>1</B>) with phenyllithium and subsequently with aqueous hydrogen peroxide in acetic acid. The oxide <B>3</B> reacted with lithium diisopropylamide (LDA) and then with several electrophiles to afford regiospecifically ortho-substituted compounds in moderate yields, which were converted to unsymmetrical 2-and 2,3′-substituted 1,1′-biaryls and triphenylphosphine oxide (<B>1</B>).

• 公益社団法人 日本化学会の論文

著者

• Furukawa Naomichi

  Department Of Chemistry And Tsukuba Advanced Research Alliance Center University Of Tsukuba

• Ogawa Satoshi

  Department Of Anatomy And Neuroscience Osaka University Medical School

• Tajiri Yoko

  Department of Chemistry, University of Tsukuba

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