A new type of reductive cleavage of disulfide in quadruply ortho-substituted diphenyl disulfide by neighboring thiolate anion.
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概要
- 論文の詳細を見る
The reaction of bis[2,6-bis(bromomethyl)phenyl] disulfide with thiourea or sodium sulfide showed an unusual reductive. cleavage of disulfide linkage with elimination of bromine by neighboring-group participation of the generated thiolate anion. Its reaction gave the structurally intriguing thiols which indicated the facile anodic oxidation.
- 公益社団法人 日本化学会の論文
著者
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Furukawa Naomichi
Department Of Chemistry And Tsukuba Advanced Research Alliance Center University Of Tsukuba
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Fujihara Hisashi
Department Of Applied Chemistry Kinki University
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Chiu Jer-jye
Department Of Chemistry University Of Tsukuba
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