The Reaction of Sulfenyl Chlorides with Thioethers. III. The Configuration and the Isomerization of <I>cis</I>- and <I>trans</I>-α-Methylthio-β-phenylthiostyrenes

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概要

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• Various α-methylthio-β-arylthiostyrenes were prepared by the action of arenesulfenyl chloride on α-methylthiostyrene. The configuration of the stereoisomers of the styrene derivatives was determined by studying the nuclear Overhauser effect in the proton magnetic resonance. The relative stabilities of α-methylthio-β-phenylthiostyrene isomers were determined by equilibrating with the aid of hydrogen chloride at various temperatures.

• 公益社団法人 日本化学会の論文

著者

• Oki Michinori

  Department Of Chemistry Faculty Of Science Okawama University Of Science

• Kobayashi Keiji

  Department Of Chemistry College Of Arts And Sciences The University Of Tokyo

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