The Reaction of α-Carbonyl Sulfides with Bases. I. The Reaction between α-Carbonyl Sulfides with Thiolates
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概要
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It is found that carbonyl compounds, such as ketones and esters, bearing an alkyl(or aryl)thio group at the α-position, are smoothly reduced to the parent carbonyl compounds by the action of the thiolate anion. α-Halo or α,α-dihalo ketones are similarly reduced with the thiolate, probably <I>via</I> the corresponding sulfides. The mechanism of the reaction is discussed.
- 公益社団法人 日本化学会の論文
著者
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Oki Michinori
Department Of Chemistry Faculty Of Science Okawama University Of Science
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Nakamura Atsuko
Department of Biochemistry, Kyoto Prefectural University of Medicine
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Nakamura Atsuko
Department of Chemistry, Faculty of Science, The University of Tokyo
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Funakoshi Wataru
Department of Chemistry, Faculty of Science, The University of Tokyo
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