The Reaction of Sulfenyl Chlorides with Thioethers. II. Kinetic Studies

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概要

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• The rates of the reaction of methyl α-phenethyl sulfide with benzenesulfenyl chloride were measured by means of product analyses. It was found that the reaction was general-acid-catalyzed and autocatalyzed. The rate-determining step was suggested to be the formation of a sulfonium ion derived from the reactants. Mechanisms for the formations of the products are suggested.

• 公益社団法人 日本化学会の論文

著者

• Oki Michinori

  Department Of Chemistry Faculty Of Science Okawama University Of Science

• Kobayashi Keiji

  Department Of Chemistry College Of Arts And Sciences The University Of Tokyo

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