Syntheses of Acylurea Derivatives as Model Compounds for a Highly Specific Organic Reaction
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概要
- 論文の詳細を見る
Some types of acylurea derivatives were prepared as model compounds for a highly specific organic reaction by molecular association. When ethyl chloroacetate was treated successively with <I>o</I>-aminobenzenethiol (<B>4</B>) and chloroacetyl isocyanate (<B>1</B>) under mild conditions, triacylurea derivative (<B>9</B>) was obtained in total 84% yield. It was found that the use of "amino acid amide and oxalyl chloride" method led to the formation of diacylurea derivative (<B>11</B>) in high yield.
- 公益社団法人 日本化学会の論文
著者
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Mukaiyama Teruaki
Laboratory of Organic Chemistry Tokyo Institute of Technology
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Mukaiyama Teruaki
Laboratory of Organic Chemistry, Tokyo Institute of Technology
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Noguchi Shigeru
Laboratory of Organic Chemistry, Tokyo Institute of Technology
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Endo Tadashi
Laboratory of Organic Chemistry, Tokyo Institute of Technology
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