Reactions of Vinyloxyboranes. A Convenient Method for the Preparation of β-Hydroxy Thiolesters, Esters and Ketones
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概要
- 論文の詳細を見る
It was found that the reaction of thioboronites with carbonyl compounds and ketene proceeds with the initial formation of vinyloxyboranes (VII). The boranes were found to be important intermediates for the formation of β-hydroxythiolesters by the reaction with various carbonyl compounds. Vinyloxyborane derivatives can be alternatively prepared by the reactions of trialkylboranes and α-diazocarbonyl compounds. The boranes similarly reacted with carbonyl compounds to give β-hydroxyketones and β-hydroxyesters.
- 公益社団法人 日本化学会の論文
著者
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Mukaiyama Teruaki
Laboratory of Organic Chemistry Tokyo Institute of Technology
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Inomata Katsuhiko
Laboratory of Organic Chemistry, Tokyo Institute of Technology
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Muraki Masayoshi
Laboratory of Organic Chemistry, Tokyo Institute of Technology
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