A Selective Phosphorylation by Means of α-Bromocyano acetamides and Trialkyl Phosphites
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概要
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A method of selective phosphorylation by means of α-bromocyanoacetamides and trialkyl phosphites was devised. In this method, various phosphates, pyrophosphates and phosphoramidate were obtained in excellent yields under mild conditions without isolating the intermediate, enol-phosphate.<BR>The use of dibromocyanoacetamide in place of monobromocyanoacetamide produced the same results, the yields being, however, less.<BR>A new method for the preparation of monobromocyanoacetamide was also described.
- 社団法人 日本化学会の論文
著者
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Mukaiyama Teruaki
Laboratory of Organic Chemistry Tokyo Institute of Technology
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Hata T.
Laboratory of Organic Chemistry Tokyo Institute of Technology
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