Sulfenylation of Active Methylene Compounds with Sulfenamides
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概要
- 論文の詳細を見る
Equimolar reactions of sulfenamides derived from secondary alkylamines with active methylene compounds afforded mono-sulfenylated compounds in good yields. The reactions of 2 mol of sulfenamides derived from imides with 1 mol of active methylene compounds in the presence of a base gave di-sulfenylated compounds. It was found that α-mono-sulfenylated ketones were prepared by the reactions of enamines with sulfenamides derived from imides. α-<I>gem</I>-Di-sulfenylated ketones were prepared by the reactions of α-mono-sulfenylated ketones with sulfenamides derived from imides in the presence of a base. The preparation and reactions of <I>N</I>-phenylthiobenzamidine hydrochloride were also examined.
- 公益社団法人 日本化学会の論文
著者
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Kobayashi Susumu
Laboratory of Nutritional Biochemistry, Graduate School of Agricultural and Life Sciences, The Unive
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Mukaiyama Teruaki
Laboratory of Organic Chemistry Tokyo Institute of Technology
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Kumamoto Takanobu
Laboratory of Organic Chemistry, Tokyo Institute of Technology
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