Studies on Nitrile Salts. III. Dimerization of Nitriles Having No α-Hydrogen with Hydrogen Chloride
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概要
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The reaction of nitriles having no α-hydrogen, such as aromatic nitriles and thiocyanates, with hydrogen chloride was investigated. Benzonitrile, <I>p</I>-tolunitrile, <I>m</I>-tolunitrile and some thiocyanates gave analytically pure 2:2 adducts in their reactions with HCl in a sealed glass tube at 30–60°C. The structure of the adducts was elucidated on the basis of NMR analysis and the mechanism of the generalized dimerization of nitriles was discussed.
- 公益社団法人 日本化学会の論文
著者
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Miyake Mikio
Department Of Surgery Tamano Mitsui Hospital
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Yanagida Shozo
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Katagiri Ichiro
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Komori Saburo
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Fujita Tetsuo
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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Ohoka Masataka
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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