Fouling mechanism in liquid phase oxidation of carbon monoxide catalyzed by palladium(II) salts in acetic acid solvents.
スポンサーリンク
概要
- 論文の詳細を見る
The fouling mechanism during catalytic activity in the liquid phase oxidation of carbon monoxide has been investigated using catalytic acetic acid solutions containing palladium(II) salts and lithium nitrate as oxidants. The fouling phenomenon becomes understandable upon the recognition that the active palladium catalysts react with the nitrite ion formed during the oxidation reaction to produce inactive-stable complexes.
- 公益社団法人 日本化学会の論文
著者
-
SAKURAI Katsumi
Department of Basic Sciences, The University of Tokyo
-
Matsumoto Tetsuo
Department Of Agricultural Chemistry Faculty Of Agriculture Nagoya University
-
Imanaka Toshinobu
Department Of Chemical Engineering Faculty Of Engineering Science Osaka University
-
Kimura Toshio
Department Of Applied Chemistry Faculty Of Science And Technology Keio University
-
Teranishi Shiichiro
Department of Chemical Engineering, Faculty of Engineeing Science, Osaka University
-
Matsumoto Tetsuo
Department of Chemical Engineering, Faculty of Engineering Science, Osaka University
-
Sakurai Katsumi
Department of Chemical Engineering, Faculty of Engineering Science, Osaka University
関連論文
- Mechanisms Underlying Mechanical Responses to Ephedra herb of Isolated Rabbit Urinary Bladder and Urethra, a Possible Stress Urinary Incontinence Therapeutic
- EFFECTS OF PREGNANCY, DELIVERY AND LACTATION IN HYPERPROLACTINEMIA WITH PROLACTIN PRODUCING PITUITARY ADENOMA
- A New Polarimeter for Dilute Aqueous Solutions : The Improved Null-Method Compensation for the Optical Rotatory Power by the Faraday Effect of a Sample
- Spectral Narrowing of Atomic Resonance by Recurrent Excitation Spectroscopy : Feedback from Atom to Radiation Field via Digital-Data Processing
- Doppler-Free Saturated Selective Reflection with Copropagating Pump-Probe Method
- New Type of Doppler Free Spectroscopy by Heterodyne Detection of Backward-Scattered Light from Velocity-Selected Atoms
- Fabrication of Textured Bismuth Sodium Titanate Using Excess Bismuth Oxide
- Stark Effect of Vibration-Rotation Lines of Formaldehyde Observed by a 3.5μm Laser
- Isotope Shift of Neon in the 3.39μm Maser Transition
- High Resolution Spectroscopy of Formaldehyde by a Tunable Infrared Maser
- A Laser Technique for State-Selected Time-of-Flight Analysis by Pseudo-Random Modulation
- Primary signet-ring cell carcinoma of the urinary bladder inducing renal failure
- Efficacy of transurethral needle ablation of the prostate for the treatment of benign prostatic hyperplasia
- Newly Developed Ultrasonic Aspirator and Its Application for Endoscopic Surgery
- Catecholamine in Congestive Heart Failure (Report I)
- Stark Effect of the Absorption Line of Methane Observed by the 3.391μm He-Ne Maser
- Enantioselective Hydrogenation of (E)-α-Phenylcinnamic Acid over Cinchonidine-Modified Palladium Catalysts
- Semiclassical Monte Carlo Path Integration in the Real-Time Domain:A Classical Trajectory Method for Describing Coherent Ultrashort Phototrasitins of Molecules
- Allantoin metabolism in soybean plants as influenced by grafts, a delayed inoculation with Rhizobium, and a late supply of nitrogen-compounds
- Effects of exogenous nitrogen-compounds on the concentrations of allantoin and various constituents in several organs of soybean plants
- Distribution and change in the contents of allantoin and allantoic acid in developing nodulating and non-nodulatng soybean plants
- Third-Order Temporal Correlation of Rayleigh Scattering
- Tunable Infrared Maser Spectrometers
- The Pressure Dependence of Absorption Coefficient in Organic Gases at 3.3913 μm and 3.5070 μm.
- In utero diagnosis of an aneurysm of the vein of Galen causing hydrocephalus and heart failure
- Porous Phosphor Thin Films of Oxyfluoride SiO_2-BaMgF_4 : Eu^ Glass-Ceramics Prepared by Sol-Gel Method
- Dynamic Selective Reflection from a Low-Density Atomic Vapor
- Hyperfine Spectrum of Xenon in the 3.5-μm Maser Transition
- 0ptical Collision Diameters of H_2CO and CH_4 Measured by the Infrared Maser Spectrograph
- Surface composition of SnO2-ZrO2 binary oxide catalyst and its selectivity for C3H6-NO reaction.
- Aromatic Substitution of Olefins. XXII. Unusual Reaction of p-Bromostyrene with Benzene in the Presence of Palladium(II) Acetate
- X-Ray Photoelectron Spectroscopic Studies of Catalysts — Supported Cobalt Catalysts —
- Aromatic Substitution of Olefin. X. Formation of Biphenyl Derivatives by Means of Olefin-Palladium Chloride Complexes and Silver Nitrate
- Catalytic Transformation of Cyclohexene Hydroperoxides to Epoxy Alcohols with Vanadyl Acetylacetonate
- Effect of ZnO addition on cobalt-alumina interaction species.
- Hydrogenation activity and selectivity of cobalt boride and cobalt nickel binary boride catalysts.
- Partial hydrogenation of acetylenes on modified nickel boride catalysts.
- Effect of pore diffusion in liquid-phase enantioselective hydrogenation with Ni-SiO2 catalysts.
- The effect of crystallite size of nickel on the enantioselectivity of modified nickel catalysts.
- The catalytic reduction of nitrogen oxide by carbon monoxide over metal oxide catalysts - The correlation of the activities with the surface states of metal oxides.
- The Distribution of the Acid Strength on Zeolite Catalyst — Estimation from the Heats of Adsorption —
- The Isomerization of Propylene Oxide on Metal Oxides and Silica-Magnesia Catalysts
- The C–O Bond Cleavage of Allyl Ethers by Rhodium Compounds
- Infrared Spectroscopic Studies on Vaska Complex using Heavy Oxygen
- The effect of the heat treatment of Pd thin film alloy on the hydrogenation of olefins.
- Oxidation by Transition Metal Complexes. VI. Oxidation of Cyclohexenes Catalyzed by Rhodium Complexes
- The Codimerizations of Styrene with Vinyl Compounds Catalyzed by Olefin-palladium(II) Chloride Complexes
- The Codimerization of Styrene with Ethylene Catalyzed by Olefin-palladium(II) Chloride Complexes
- X-ray photoelectron spectroscopic studies of catalysts. Chromia-alumina catalysts.
- Selective deoxygenation of various N-O bonds catalyzed by rhodium carbonyl clusters in the presence of H2O and CO and their heterogenization using amino-substituted polystyrenes.
- The Isomerization of Propylene Oxide on Metal Phosphate Catalysts
- Oxidation by Transition Metal Complexes. III. Oxidation of Cinnamaldehyde Catalyzed by Rhodium Compounds
- Oxidation by Transition Metal Complexes. II. Oxidation of Styrenes Catalyzed by Rhodium Compounds
- Characterization of active sites in sulfided molybdenum/alumina hydrodesulfurization catalysts.
- Structure dependence in the hydrogenation of acetylene over columnar Pd film.
- Oxidation by Transition Metal Complexes. V. Oxidation of Vinyl Esters Catalyzed by Rhodium Complex.
- Fouling mechanism in liquid phase oxidation of carbon monoxide catalyzed by palladium(II) salts in acetic acid solvents.
- Oxidation by Transition Metal Complexes. I. Oxidation of Styrene and Triphenylphosphine Catalyzed by O2-Ir Complex
- Microdegree Azimuth Polarimeter using Optical Heterodyne Detection