Oxidation by Transition Metal Complexes. I. Oxidation of Styrene and Triphenylphosphine Catalyzed by O<SUB>2</SUB>-Ir Complex

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概要

• 論文の詳細を見る

• In order to investigate the oxidation reaction which is catalyzed by transition metal complexes in a homogeneous system under mild conditions, the oxidation reactions of styrene and triphenylphosphine catalyzed by various iridium complexes have been studied. The Vaska complex (IrX(CO)(PPh<SUB>3</SUB>)<SUB>2</SUB>) and the biphosphine chelate complex have been found to be effective as oxidation catalyst. It was found that the SnCl<SUB>3</SUB> ligand which has a strong <I>trans</I> effect promotes the oxidation of styrene. For the sake of comparison with the iridium compounds, oxidation with palladium salts was also studied.

• 公益社団法人 日本化学会の論文

著者

• Fujiwara Yuzo

  Department Of Applied Chemistry Faculty Of Engineering Hiroshima University

• Imanaka Toshinobu

  Department Of Chemical Engineering Faculty Of Engineering Science Osaka University

• Teranishi Shiichiro

  Department of Chemical Engineering, Faculty of Engineeing Science, Osaka University

• Takao Kiyotomi

  Department of Chemical Engineering, Faculty of Engineering Science, Osaka University

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