Oxidation by Transition Metal Complexes. III. Oxidation of Cinnamaldehyde Catalyzed by Rhodium Compounds

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概要

• 論文の詳細を見る

• The catalytic activity of RhCl(PPh<SUB>3</SUB>)<SUB>3</SUB> and RhCl(CO)(PPh<SUB>3</SUB>)<SUB>2</SUB> for oxidations of styrene and cinnamaldehyde has been studied. Under oxygen atmosphere, these complexes can cause catalytically oxidation of cinnamaldehyde to give benzaldehyde, glyoxal, benzene and styrene. The reaction is complicated because decarbonylation reaction takes place with oxidation, and the carbonyl complex formed plays a catalytic role for the oxidation.

• 公益社団法人 日本化学会の論文

著者

• Fujiwara Yuzo

  Department Of Applied Chemistry Faculty Of Engineering Hiroshima University

• Imanaka Toshinobu

  Department Of Chemical Engineering Faculty Of Engineering Science Osaka University

• Teranishi Shiichiro

  Department of Chemical Engineering, Faculty of Engineeing Science, Osaka University

• Wayaku Masami

  Department of Chemical Engineering, Faculty of Engineeing Science, Osaka University

• Takao Kiyotomi

  Department of Chemical Engineering, Faculty of Engineering Science, Osaka University

• Fujiwara Yuzo

  Department of Chemical Engineering, Faculty of Engineering Science, Osaka University

• Wayaku Masami

  Department of Chemical Engineering, Faculty of Engineering Science, Osaka University

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