A remarkable solvent effect on the reductive silylation of carboxylic esters. Preparation of 1,1-bis(trimethylsilyl)-1-alkanols.
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概要
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1,1-Bis(trimethylsilyl)-1-alkanols were obtained in good yields when ethyl esters of the corresponding carboxylic acids were treated with sodium suspension and chlorotrimethylsilane in refluxing tetrahydrofuran followed by acidic hydrolysis.
著者
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Minami Naoki
Department Of Applied Quantum Physics And Nuclear Engineering Graduate School Of Engineering Kyushu
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ABE Toru
Department of Agricultural Chemistry, The University of Tokyo
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Kuwajima Isao
Department Of Chemistry Tokyo Institute Of Technology
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Sato Toshio
Department Of Anatomy Sapporo Medical University
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