Conversion of carbon-sulfur linkages into carbon-silicon ones via reductive silylation. Preparation of silyl enol ethers of acyltrimethylsilanes.
スポンサーリンク
概要
- 論文の詳細を見る
Reductive cleavage of carbon–sulfur linkages of silyl enol ethers of thiocarboxylic S-esters can be induced by treatment with sodium or potassium–sodium alloy in the presence of chlorotrimethylsilane, and the corresponding silyl enol ethers of acyltrimethylsilanes can be prepared in high yields.
著者
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Kuwajima Isao
Department Of Chemistry Tokyo Institute Of Technology
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Mori Akio
Department Of Clinical Research Center National Sagamihara Hospital
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Kato Masahiro
Department Of Analytical Chemistry Meiji College Of Pharmacy:faculty Of Pharmaceutical Sciences Chib
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Kato Masahiro
Department of Chemistry, Tokyo Institute of Technology
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Mori Akio
Department of Chemistry, Tokyo Institute of Technology
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