NEW METHOD FOR MEASURING TERNARY VAPOR-LIQUID EQU1RIBRIA:DEW, BUBBLE AND CONDENSATION POINT METHOD

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概要

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• A new method for determination of vapor-liquid equilibria in ternary systems is proposed, based on the following two relations.(1) The bubble point of the equilibrium liquid composition should be equal to the dew point of the equilibrium vapor composition.(2) The condensation point of the equilibrium liquid composition should be the bubble point of the equilibrium vapor composition. Using these relations described above, vapor-liquid equilibrium relations in ternary systems can be determined from the dew, bubble and condensation point data without the use of other assumptions. A new apparatus was designed for the simultaneous measurement of dew, bubble and condensation points. This apparatus makes it possible to measure dew, bubble and condensation points at any desired composition without analysis. Using the present method, vapor-liquid equilibrium relations were determined from experimental dew, bubble and condensation point data at atmospheric pressure for the ternary systems acetone-methanoUwater and methanol-ethanof-dioxane.

• 公益社団法人 化学工学会の論文

著者

• Sato Takao

  Department Of Biological Science And Technology Faculty Of Engineering The University Of Tokushima

• Kato Masahiro

  Department Of Analytical Chemistry Meiji College Of Pharmacy:faculty Of Pharmaceutical Sciences Chib

• HIRATA MITSUHO

  Department of Chemical Engineering, Faculty of Engineering, Tokyo Metropolitan University

• KATO MASAHIRO

  Department of Industrial Chemistry, Faculty of Engineering, Tokyo Metropolitan University

• KONISHI HITOSHI

  Department of Industrial Chemistry, Faculty of Engineering, Tokyo Metropolitan University

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