ジオキソピロリンを利用した種々の含窒素複素環化合物の合成
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This article deals with the synthetic utility of dioxopyrrolines in the field of heterocyclic chemistry, especially on focusing carbon-carbon bond forming reactions, in which they acted as dienophiles on Diels-Alder reaction and also as enophiles on photocycloaddition reaction yielding hydroindoles and 2- azabicyclo [3. 2. 0] heptanes respectively. The latter compounds, strained cyclobutanes, underwent skeletal rearrangements to form various heterocyclic compounds such as hydroindoles, azatropolones, azanorbornenes, azanonanes, dihydropyridones, and dihydropyridines. This methodology was successfully applied to total synthesis of erythrina alkaloids.
- 社団法人 有機合成化学協会の論文
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- ジオキソピロリンを利用した種々の含窒素複素環化合物の合成