The Synthesis of New Polymer Derivatives of ATP by Radical Copolymerization and Their Coenzymic Activity

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概要

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• Three polymerizable ATP derivatives, N6-[N-(6-methacrylamidohexyl)carbamoylmethyl]-, N6-[N-[2-[N-(2-methacrylamidoethyl)carbamoyl]ethyl]carbamoylmethyl]-, and N6-[N-[N-(2-hydroxy-3-methacrylamidopropyl)carbamoylmethyl]carbamoylmethyl]-ATP, were synthesized and radically copolymerized with comonomers [acrylamide, N-(2-hydroxyethyl)-, N-ethyl-, N, N-diethylacrylamide, acrylic acid, and 6-methacrylamido hexylammonium chloride] to obtain 18 new polymer derivatives of ATP. The molecular weight distributions were controlled by appropriate initiator concentrations. The monomeric and polymeric ATP derivatives were all coenzymically active against both hexokinase and glycerol kinase. The observed coenzymic activities (Km and Vmax) are discussed in connection with the structures of the derivatives.

• 社団法人 日本農芸化学会の論文

著者

• Maeda Hidekatsu

  Fermentation Research Institute Agency Of Industrial Science And Technology

• Yamazaki Yoshimitsu

  Fermentation Research Institute Agency Of Industrial Science And Technology

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