Raman spectroscopic study of benitoite-type compounds(<Feature>Glass and Ceramic Materials for Photonics)

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概要

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• Raman scattering measurements were performed in the benitoite-type BaTiSi_3O_9, BaZrSi_3O_9, BaSnSi_3O_9 and tetragermanatetype BaGe_4O_9 phases in order to elucidate the spectroscopic and structural features of D_<2/v>G (T_3O_9)-type compounds (expressed by Smith's notation) with the GO_6 octahedral unit isolated by the T_3O_9 ring. The Raman band assignments in middle and high wavenumber region wes also carried out. In addition, the wavenumber of antisymmetric stretching vibration mode, ν_<as>, for Si-O-G bond was calculated by means of combination of the simple molecular model and Badger's rule, and compared with the experimental results. It was suggested that the v_<as> was governed by the force constant of T-O_<ax> bond, which was connected with the G^<4+>.

• 2008-10-01

著者

• TAKAHASHI YOSHIHIRO

  Department of Pediatrics, Odate Municipal General Hospital

• IWASAKI Kenichiro

  Department of Applied Physics, Tohoku University

• MASAI Hirokazu

  Department of Applied Physics, Tohoku University

• FUJIWARA Takumi

  Department of Applied Physics, Tohoku University

• Fujiwara Tamiya

  Deparment Of Electrical And Electronic Engineering Iwate University

• TAKAHASHI Yoshikazu

  Ibaraki Prefectural University of Health Sciences

• Takahashi Y

  Ulvac Japan Ltd. Ibaraki Jpn

• Takahashi Yoshihiro

  Department Of Applied Physics School Of Engineering Tohoku University

• Masai Hirokazu

  Department Of Applied Physics School Of Engineering Tohoku University

• Fujiwara T

  Department Of Electrical Engineering Faculty Of Engineering Iwate University

• Fujiwara T

  Department Of Applied Physics School Of Engineering Tohoku University

• Fujiwara T

  Toyota Technological Inst. Nagoya Jpn

• Takahashi Y

  Tanaka Solid Junction Project Erato Japan Science And Research Corporation

• Fujiwara Takumi

  Department Of Applied Physics School Of Engineering Tohoku University

• Takahashi Yoichi

  Department Of Nuclear Engineering Faculty Of Engineering University Of Tokyo

• Iwasaki Kenichiro

  Department Of Applied Physics Tohoku University

• Takahashi Yukihiro

  Central Research Laboratory Matsushita Electric Industrial Co. Ltd.

• Takahashi Y

  Department Of Applied Physics School Of Engineering Tohoku University

• Takahashi Yoshinori

  Division Of Electrical Electronic And Information Engineering Osaka University

• Takahashi Y

  National Inst. Animal Health Ibaraki Jpn

• Takahashi Y

  Department Of Molecular & Materials Sciences Kyushu University

• Fujiwara Takumi

  Dep. Of Applied Physics Tohoku Univ.

• Takahashi Yoshihiro

  Department Of Applied Physics Osaka City University

• Masai Hirokazu

  Department of Applied Physics, School of Engineering, Tohoku University

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