76(P-69) Acanthopanax属植物のトリテルペン成分(ポスター発表の部)
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概要
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Acanthopanax genus belongs to Araliaceae family, just as Panax ginseng, and generally has prickly stem bearing five leaflets (palmate), and umbel-shape flower. About 30 kinds of Acanthopanax species are found in East Asia and South Asia on the world. The root and stem barks of this plant are used as tonic and prophylactic in oriental herbal medication from olden times. In the course of studies on the phytochemical constituents of Acanthopanax genus, we previously reported the isolation and structural elucidation of triterpene glycosides from six kinds of Acanthopanax genera (4 species originated form Korea, 2 species from Japan, and 1 species from Taiwan). Their constituents could be classified into three groups, according to their varieties of triterpene constituents. The first group contains normal triterpene glycoside entirely (A. korenum and A. trifoliatus). The second group has no normal lupan but 3,4-seco-lupane (A. divaricatus var. albeofructus, A. divaricatus var. sachunensis and A. senticosus forma inermis). The third group contains only oleanane glycoside (A. japonicus). In this time, we report herein the isolation and structural determination of triterpenoids newly obtained from A. senticosus forma inermis cultivated for medicinal use in Korea, A. divaricatus var. sachunensis recently found as a new Acanthopanax species in Sachun city located in Korea, and A. japonicus distributed in Kyushu of Japan. The dried leaves of these plants were extracted with MeOH, followed by evaporation to give extracts. The respective MeOH extracts were passed through a Diaion HP-20, sillica gel, Sephadex LH-20 and Chromatorax ODS column chromatographies succesively to give four new 3,4-seco-lupane glycosides [inermoside (1), 1-deoxychiisanoside (2), 24-hydroxychiisanoside (3) and 11-deoxyisochiisanoside (4)] from A. senticosus forma inermis, a novel 3,4-seco-migrated lupane bidesmoside [inermoside (5)] from A. divaricatus var. sachunensis, and six new oleanane glycosides [acanjaposide A-F (6-11)] from A. japonicus. These data are very useful for chemotaxanomy of Acanthopanax species from a phytochmical point of view.
- 天然有機化合物討論会の論文
- 2000-10-01
著者
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野原 稔弘
熊本大学薬学部
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野原 稔弘
熊本大・薬
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野原 稔弘
熊本大学 医薬
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野原 稔弘
崇城大薬
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野原 稔弘
熊本大薬
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野原 稔弘
熊本大 大学院 医学薬学研究部
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陸 昌洙
熊本大学 薬
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陸 昌洙
慶煕大・薬
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朴 相勇
Department of Natural Product Evaluation, Korea Food and Drug Administration
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Chang Seung-Yeup
Department of Natural Product Evaluation, Korea Food and Drug Administration
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Chang Seung-yeup
Department Of Natural Product Evaluation Korea Food And Drug Administration
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朴 相勇
Department Of Natural Product Evaluation Korea Food And Drug Administration
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野原 稔弘
能本大学薬学部
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