Synthesis and Crystal Structure of a Novel Organic Ion-Complex Crystal for Second-Order Nonlinear Optics
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概要
- 論文の詳細を見る
The novel organic ion-complex crystal composed of protonated merocyanine and p-toluenesulfonate anion, i.e., 1-methyl-4-(2-(4-hydroxyphenyl)vinyl)pyridinium 4-toluenesulfonate (MC-PTS), was synthesized for second-order nonlinear optics. Crystal structure analysis revealed that MC-PTS crystallized in the space group of P1, i.e., the most desired space group for waveguide applications where molecular dipoles are perfectly aligned in one direction. It was also pointed out that the tetrahedral sulfonate anion plays the role of a chiral handle to give noncentrosymmetric space groups.
- 社団法人応用物理学会の論文
- 1990-06-20
著者
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Kato Masatune
Department Of Physics Faculty Of Science Hiroshima University
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Okada S
Department Of Polymer Science And Engineering Graduate School Of Science And Engineering Yamagata Un
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MATSUDA Hiro
National Institute of Advanced Industrial Science and Technology
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Kato M
Toyota Central R&d Laboratories Inc.
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Aoki Makoto
Department Of Industrial Chemistry Faculty Of Engineering University Of Tokyo
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Kato M
Japan Atomic Energy Res. Inst. Ibaraki Jpn
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Kato Masatsune
Department Of Applied Physics Faculty Of Engineering Tohoku University
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OKADA Shuji
Research Institute for Polymers and Textiles
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MATSUDA Hiro
Research Institute for Polymers and Textiles
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NAKANISHI Hachiro
Research Institute for Polymers and Textiles
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KATO Masao
Research Institute for Polymers and Textiles
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Nakanishi Hachiro
Institute Of Multidisciplinary Research For Advanced Materials Tohoku University
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MASAKI Atsushi
Research Division, The Green Cross Corporation
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Kato M
Advanced Research Laboratory Hitachi Ltd.
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Okada S
Shimadzu Corp. Kyoto Jpn
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Matsuda H
Department Of Applied Chemistry Faculty Of Engineering Osaka Institute Of Technology
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Masaki Atsushi
Research Division The Green Cross Corporation
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Masaki Atsushi
Department Of Applied Physics Univetsity Of Tokyo
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Masaki Atsushi
Research Center For Development Of Far-infrared Region Fukui University
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Masuhara A
Institute For Multidisciplinary Research For Advanced Materials Tohoku University
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Otsuka M
Sumita Optical Glass Inc.
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Nakanishi H
Toshiba Ceramics Co. Ltd. Kanagawa Jpn
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MURAMATSU Ryoji
Sumita Optical Glass Inc.
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OTSUKA Masaaki
Sumita Optical Glass Inc.
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Nakanishi H
Department Of Electrical Engineering Science University Of Tokyo
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Muramatsu Ryoji
Sumita Optical Glass Inc.:(present Address)tokin Corp.
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Kato Masashi
Department of Applied Physics, Graduate School of Engineering, Tohoku University
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