Studies on the [2,3]-Meisenheimer Rearrangement of 2-Vinylazetidine N-Oxides
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概要
- 論文の詳細を見る
Oxidation of 2-vinylazetidine 6a with m-chloroperbenzoic acid (mCPBA) in methylene dichloride (CH_2Cl_2) gave a mixture of dihydro-7H-[1,2]oxazepine 9a and the nitrone 10a. It was clarified that the former was obtained via the [2,3]-Meisenheimer rearrangement of the corresponding cis-N-oxide A, and the latter was formed by successive oxidation of the isoxazolidine 11 formed via the [1,2]-Meisenheimer rearrangement of the corresponding trans-N-oxide B.
- 公益社団法人日本薬学会の論文
- 1998-05-15
著者
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Kurihara T
Osaka University Of Pharmaceutical Sciences
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米田 龍司
Agroscience Research Laboratories Sankyo Co. Ltd.
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HARUSAWA Shinya
Osaka University of Pharmaceutical Sciences
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ARAKI Lisa
Osaka University of Pharmaceutical Sciences
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YONEDA Ryuji
Osaka University of Pharmaceutical Sciences
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KURIHARA Takushi
Osaka University of Pharmaceutical Sciences
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Araki L
Osaka University Of Pharmaceutical Sciences
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