Steroids. VII. Photolysis of 3β, 5α-Diacetoxy-6-nitriminocholestane
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概要
- 論文の詳細を見る
Photolysis of 3β, 5α-diacetoxy-6-nitriminocholestane (1) gives 3β, 5α-diacetoxycholestan-6-one (2), 3β-acetoxy-5α-cholestan-6-one (8), 3β, 5α-diacetoxy-6-hydroximinocholestane (9), and 3β, 5α-diacetoxy-6-iminocholestane (10) as nitrate. The structure of 10 is proved by its catalytic reduction and subsequent acetylation to 6β-acetamido-3β, 5α-diacetoxycholestane (11). The structure of 9 is identified by its reduction with titanium trichloride to 10. Also, formation pathways of these photo-products are briefly examined.
- 公益社団法人日本薬学会の論文
- 1976-08-25
著者
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恩田 政行
School of Pharmaceutical Sciences, Kitasato University
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恩田 政行
Shenyang Pharmaceutical University
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竹内 啓二
School Of Pharmaceutical Sciences Kitasato University
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