Studies on Fungal Polysaccharides. XIX. Chemical Structure of a Water Soluble Polysaccharide from the Cell Wall of Cladosporium trichoides
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Major water-soluble polysaccharide obtained from the cell wall of Cladosporium trichoides by diethylaminoethyl-cellulose column fractionation is a heteroglycan, [α]^20_D+50°(c=1,H_2O), which is composed of D-galactose, D-glucose, D-mannose, and small amount of L-rhamnose (1.4 : 1.4 : 1.0 : 1.0). The results of periodate oxidation, Smith-type degradation, methylation, and gas-liquid chromatography-mass spectrometry spectra show that the polysaccharide has branched structure and contains 1,2-, and 1,2,6-linked galacto-furanosyl, 1,3,6-linked mannopyranosyl, and a small amount of 1,4-linked glucopyranosyl residues as the main units. The terminal residues are glucopyranosyl and mannopyranosyl residues.
- 公益社団法人日本薬学会の論文
- 1976-08-25
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