Studies on Organometallic Compounds. I. Insertion Reaction of Diketene into N-Si Bond of Silylated Amides
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概要
- 論文の詳細を見る
Insertion of diketene into the N-Si bond of silylated secondary amides (Ia-d) followed by hydrolysis afforded N-acetoacetyl derivatives (IVa-d) of the corresponding amides in good yields, respectively. In the reaction with silylated primary amides (Va-c), insertion of diketene into the N-Si bond with subsequent reaction of another mole of diketene resulted in the formation of the corresponding 4-pyrone derivatives (VIa-c), respectively.
- 公益社団法人日本薬学会の論文
- 1976-06-25
著者
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山本 豊
Tohoku College of Pharmacy
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木村 仁
Pharmaceutical Institute, Tohoku University
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木村 仁
Pharmaceutical Institute Tohoku University
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- Studies on Organometallic Compounds. I. Insertion Reaction of Diketene into N-Si Bond of Silylated Amides