Studies on Organometallic Compounds. II. Facile and Convenient Method for the Synthesis of Iodoazines through Iododestannation of Trimethylstannylazines
スポンサーリンク
概要
- 論文の詳細を見る
Trimethylstannyl and bis (trimethylstannyl) derivatives of pyridine, quinoline, and isoquinoline were prepared from the corresponding halo and dihalo (chloro or bromo) derivatives and trimethylstannyl sodium, which was generated in situ from chlorotrimethyl-stannane and sodium. These stannyl derivatives readily underwent iododestannation on treatment with iodine to produce the corresponding iodo and diiodo derivatives of pyridine, quinoline, and isoquinoline, respectively, in good yields.
- 公益社団法人日本薬学会の論文
- 1982-05-25
著者
関連論文
- Simple and Mild Method for Preparation of α-Pyridinecarboxylates and α-Pyridyl Ketones via Trimethylstannyl Derivatives
- Studies on Organometallic Compounds. VII. Reaction of Di-tert-butyl Dicarbonate with α-Trialkylstannyl Derivatives of Pyridine, Quinoline, and Isoquinoline
- 1,3-Oxazines and Related Compounds. XII. : Facile Synthesis of 2,4-Disubstituted 6H-1,3-Oxazin-6-ones
- 1,3-Oxazines and Related Compounds. X. Ring Transformation of 1,3-Oxazin-4-ones into Pyridine Derivatives
- 1,3-Oxazines and Related Compounds. VIII. Reaction of 6-Methyl-2-phenyl-4H-1,3-oxazin-4-one with Lactams and Their Derivatives
- 1,3-Oxazines and Related Compounds. VI. Synthesis and Some Reactions of 2,6-Disubstituted 4H-1,3-Thiazin-4-ones
- 1,3-Oxazines and Related Compounds. V. N-Acylacetylation of Carboxamides with the Diketene-Halotrimethylsilane System or Acyl Meldrum's Acids
- 1,3-Oxazines and Related Compounds. XIV. Facile Synthesis of 2,3,6-Trisubstituted 2,3-Dihydro-1,3-oxazine-5-carboxylic Acids and 1,4-Disubstituted 3-Acyl-β-lactams from Acyl Meldrum's Acids and Schiff Bases(Organic,Chemical)
- 1,3-Oxazines and Related Compounds. XIII. Reaction of Acyl Meldrum's Acids with Schiff Bases Giving 2,3-Disubstituted 5-Acyl-3,4,5,6-tetrahydro-2H-,3-oxazine-4,6-diones and 2,3,6-Trisubstituted 2,3-Dihydro-1,3-oxazin-4-ones(Organic,Chemical)
- Studies on Organometallic Compounds. III. Reaction of Trimethylstannylazines with Acyl Chlorides. A Novel C-C Bond Formation of Pyridine Nuclei
- Studies on Organometallic Compounds. II. Facile and Convenient Method for the Synthesis of Iodoazines through Iododestannation of Trimethylstannylazines
- 1,3-Oxazines and Related Compounds. II. Ring Contraction Reaction of 1,3-Oxazin-4-one Derivatives into 1,2,4-Triazoles and Pyrazoles
- Studies on Organometallic Compounds. I. Insertion Reaction of Diketene into N-Si Bond of Silylated Amides