On the Constituents of Linaria japonica MIQ. II. The Structure of Linaridial, a New cis-Clerodane-type Diterpene Dialdehyde
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概要
- 論文の詳細を見る
A new diterpene dialdehyde named linaridial was isolated from the ether extractive of fresh subterranean part of Linaria japonica MIq. (Scrophulariaceae), and the structure has been established as 1 on the basis of the physicochemical evidence and the chemical correlation with known 5β-methyl-cis-furano-clerodane (7). Linaridial (1) is the first example of a cis-clerodane-type diterpene isolated from the scrophulariaceous plant. The examination of the MeOH extractive of the same plant has revealed the presence of two linaridial-analogues (LJ-1 (major) and LJ-2 (minor)) along with the small amount of linaridial (1). The structures, 11 and 12,have been assigned to LJ-1 and LJ-2,which seem to be the artefacts formed secondarily from linaridial (1) during the hot MeOH extraction procedure.
- 公益社団法人日本薬学会の論文
- 1976-02-25
著者
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吉岡 一郎
Faculty Of Pharmaceutical Sciences Osaka University
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谿 忠人
富山医科薬科大学和漢薬研究所
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北川 勲
Faculty Of Pharmaceutical Sciences Osaka University
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吉原 実
大阪大学薬学部
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谿 忠人
Faculty of Pharmaceutical Sciences, Osaka University
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吉原 実
Faculty of Pharmaceutical Sciences, Osaka University
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