Facile Synthesis of (E)-Allylic Alcohols by Acid-Catalyzed Modification of the Mislow-Evans Rearrangement of Allylic Sulfoxides

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概要

• 論文の詳細を見る

• The Mislow-Evans rearrangement of α, β-and α, γ-disubstituted allylic sulfoxides (2) to (E)-allylic alcohols (4) was found to occur under acidic conditions. By combination of this method with a catalytic oxidation of allylic sulfides (1), a novel one-pot transformation of allylic sulfides (1) to 4 was achieved.

• 公益社団法人日本薬学会の論文
• 1985-06-25

著者

• 正木 幸雄

  Gifu Pharmaceutical University

• 正木 幸雄

  岐阜薬科大学:(現)名城大学薬学部薬化学教室

• 鍛治 健司

  Gifu College of Pharmacy

• 佐久間 和彦

  Gifu College of Pharmacy

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