meso-Tetra[5-(8-hydroxyquinolyl)]porphine. A Novel Porphyrin with Metal-chelating Groups in the Peripheral Region
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概要
- 論文の詳細を見る
meso-Tetra[5-(8-hydroxyquinolyl)]porphine was synthesized by the Rothemund method as a model of porphyrin with metal chelating groups in the peripheral region. The presence of three kinds of copper (II) complexes was demonstrated ; free base porphyrin with metal chelated 8-quinolinol groups and metalloporphyrin with metal chelated and unchelated 8-quinolinol groups. In dimethylformamide solution, reaction of the compound with excess copper (II) perchlorate occurred in two steps ; rapid metal chelation of the 8-quinolinol moiety and subsequent slow Cu (II) incorporation into the porphine moiety. Reaction with excess aluminum (III) nitrate under similar conditions gave free base porphyrin with Al (III) chelated 8-quinolinol groups.
- 社団法人日本薬学会の論文
- 1980-09-25
著者
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松島 美一
共立薬大
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菅田 節朗
Kyoritsu College of Pharmacy
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筒井 稔
Department Of Chemistry Texas A & M University
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松島 美一
Faculty of Pharmaceutical Sciences, Kyushu University 62
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松島 美一
Faculty Of Pharmaceutical Sciences Kyushu University
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菅田 節朗
Faculty of Pharmaceutical Sciences, Kyushu University 62
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西園寺 裕子
Faculty of Pharmaceutical Sciences, Kyushu University 62
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西園寺 裕子
Faculty Of Pharmaceutical Sciences Kyushu University 62
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