Isolation, Structure, and Synthesis of Lenthionine and Its Analogs.

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概要

• 論文の詳細を見る

• Lenthionine, an odorous substance, has been isolated from Lentinus edodes (Berk.) Sing and the structure was established as 1,2,3,5,6-pentathiepane (I). 1,2,4,6-Tetrathiepane (II) and 1,2,3,4,5,6-hexathiepane (III) were also isolated from the mushroom in minor quantities. All these cyclic methylene polysulfides were synthesized from simple starting materials. A precursor of lenthionine was isolated in crystalline form and the structure was deduced mainly on the mass spectral studies. A possible mechanism for the formation of lenthionine and its analogs from the precursor was proposed.

• 公益社団法人日本薬学会の論文
• 1967-07-25

著者

• 森田 桂

  Research Laboratories, Takeda Chemical Industries, Ltd.

• 小林 栄

  Chemical Research Laboratories Research And Development Division Takeda Chemical Industries Ltd.

• 小林 栄

  Research and Development Division, Takeda Chemical Industries, Ltd.

• 森田 桂

  Research And Development Division Takeda Chemical Industries Ltd.

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