Untersuchung uber Alkaloide von Papaveraceen. VII. Alkaloide von Corydalis incisa. (6). Uber die Struktur des Corynolins. (2).
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Die Stellungen ber beiden Methylendioxygruppe des Corynolins werden dadurch bestimmt, dass Dihydrosanguinarin aus Desoxycorynolin abgeleitet wurde. Ausserdem wurde die Stellung der quartaren Methylgruppe dadurch bestimmt, dass 2-Methyl-6,7-methylendioxynaphthalin aus dem Des-N-Produkt von Desoxycorynolin, sowie Desoxy-dihydrocorynolin durch Pyrolyse-Reaktion erhalten wurde. Die Stellung der alkoholischen Hydroxygruppe und die Konstellation des Corynolins werden aus den herangezogenen Infrarot Spektren diskutiert.
- 公益社団法人日本薬学会の論文
- 1963-10-25
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