Oxidation of 3-Hydroxypiperidines with Iodosylbenzene in Water : Tandem Oxidative Grob Fragmentation-Cyclization Reaction
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概要
- 論文の詳細を見る
Oxidation of 3-hydroxypiperidine with iodosylbenzene in water afforded 2-pyrrolidinone directly in good yields. The reaction probably involves oxidative Grob fragmentation yielding imino aldehyde, which upon hydrolysis produces 2-pyrrolidinone via a cyclization-oxidation sequence.
- 公益社団法人日本薬学会の論文
- 2004-09-01
著者
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Tada N
Faculty Of Pharmaceutical Sciences University Of Tokushima
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Miyamoto K
Faculty Of Pharmaceutical Sciences Osaka University
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Ochiai M
Faculty Of Pharmaceutical Sciences University Of Tokushima
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Ochiai Masahito
Faculty Of Pharmaceutical Sciences University Of Tokushima
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Miyamoto Kazunori
Faculty Of Pharmaceutical Sciences University Of Tokushima
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TADA Norihiro
Faculty of Pharmaceutical Sciences, University of Tokushima
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