軟ろう付用フラックスの作用機構に関する研究(第 6 報) : Ni, Fe 板上の銀塩と銅塩のフラックス作用

概要

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In previous paper, the flux action of various inorganic metal salts (chloride, sulfate and nitrate) for soldering was reported about the relation between the reaction of flux with molten Sn solder and spreadability of Sn solder on Cu plate. In this report, authors have studied the relation between the reaction of base plate (Ni, Fe) or Sn solder with flux and spreading phenomenon of Sn solder on Fe plate or Ni plate in the case of various silver salts and copper salts as flux. The results obtained were as follows : (1) The corrosion rate increases from Ni, to Cu and to Fe. (2) The effects of corrosion products on spreadability increased from FeCl_3,to FeCl_2,to NiCl_2,and to CuCl_2. (3) FeSn_2 coated on Sn solder obstructs spreading of Sn solder. (4) FeSn_2 produced by the reaction of molten Sn with Fe salt is controlled in proportion to the amount of Ag or Cu in Sn solder. (5) Spreading of Sn solder on Fe plate is affected by FeSn_2 produced at interface of Sn solder and base plate. (6) When Ni plate is used, Ni dissolves little in Sn solder and spreadability depends on the reactivity of Sn with flux.
社団法人溶接学会の論文
1974-12-05