Determination of the Stereochemistry of (-)-Koninginin A by an X-ray Analysis of Its Synthetic Sample(Organic Chemistry)
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概要
- 論文の詳細を見る
The absolute configuration of (-)-koninginin A {10-hexy1-11, 12-dioxatricyclo[7. 2. 1. 0<1, 6>]dodecane-2, 5-diol (1)}, the antibiotic metabolite of Trichoderma koningii and T. harzianum, was determined as 1S, 2R, 5S, 6S, 9S, 10S by an X-ray crystallographic analysis of its synthetic sample coupled with the established stereochemical outcome of Sharpless asymmetric dihydroxylation used as the key reaction to prepare intermediate 4.
- 社団法人日本農芸化学会の論文
- 2002-08-23
著者
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Abe Kaoru
Department Of Pathology Nagasaki University School Of Medicine
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BANDO Masahiko
Medicinal Chemistry Research Institute, Otsuka Pharmaceutical Co. Ltd
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Abe Katsushige
Second Department Of Internal Medicine Nagasaki University Graduate School Of Biomedical Sciences
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Bando M
Medicinal Chemistry Research Institute Otsuka Pharmaceutical Co. Ltd
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MORI Kenji
Insect Pheromone and Traps Division, Fuji Flavor Co., Ltd.
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BANDO Masahiko
Organic Chemistry Research Institute, Otsuka Pharmaceutical Co. Ltd.
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ABE Kaoru
Tokushima Second Factory, Otsuka Pharmaceutical Co. Ltd.
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Abe Kaoru
Second Department Of Internal Medicine Nagasaki University Graduate School Of Biomedical Sciences
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Mori Kenji
Insect Pheromone And Traps Division Fuji Flavor Co. Ltd.
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