Synthesis of the Four Stereoisomers of 7-Acetoxy-15-methylnonacosane, a Component of the Female Sex Pheromone of the Screwworm Fly, Cochliomyia hominivorax
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概要
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The four stereoisomers of 7-acetoxy-15-methylnonacosane (1), a component of the female sex pheromone of the New World screwworm fly (Cochliomyia hominivorax) were synthesized. The stereogenic center at C-15 of 1 originated from that of the enantiomers of citronellal, and that at C-7 was generated by lipase-catalyzed asymmetric acetylation of (3RS,11R)- and (3RS,11S)-17-methyl-1-trimethylsilylpentacos-1-yn-3-ol (13). Three of the stereoisomers of 1 showed equivalent good pheromone activity, while the activity of (7R,15R)-1 was weak.
- 2004-08-23
著者
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OHRUI Hiroshi
Graduate School of Life Science, Tohoku University
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OHTAKI Takashi
Graduate School of Life Sciences, Tohoku University
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Ohtaki Takashi
Graduate School Of Life Sciences Tohoku University
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Ohrui Hiroshi
Graduate School Of Life Science Tohoku University
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MORI Kenji
Insect Pheromone and Traps Division, Fuji Flavor Co., Ltd.
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BERKEBILE Dennis
U. S. Department of Agriculture, Agricultural Research Service, Midwest Livestock Insect Research Un
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CARLSON David
U. S. Department of Agriculture, Agricultural Research Service, Center for Medical, Agricultural and
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Carlson David
U. S. Department Of Agriculture Agricultural Research Service Center For Medical Agricultural And Ve
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Berkebile Dennis
U. S. Department Of Agriculture Agricultural Research Service Midwest Livestock Insect Research Unit
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Mori Kenji
Insect Pheromone And Traps Division Fuji Flavor Co. Ltd.
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