A solution of the“intrinsic problem”of diastereomer method in chiral discrimination : Development of a method for highly efficient and sensitive discrimination of chiral alcohols
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概要
- 論文の詳細を見る
Very potent fluorescent chiral labeling reagents for alcohols, (R, R)-and (S, S)-2-(anthracene-2, 3-dicarboximido)cyclohexanecarboxylic acids, were developed. By labeling with them, the enantiomeric discriminations of primary alcohols having a methyl branching at the carbon from 2 to 9 by 1H-NMR and from 2 to 16 by HPLC were achieved. Further, HPLC separations of all four optical isomers of methyl branched secondary alcohols and enantiomers of 9-nonadecanol were also achieved.
- 日本学士院の論文
著者
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Akasaka Kazuaki
Graduate School Of Life Science Tohoku University
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Ohrui Hiroshi
Graduate School Of Life Science Tohoku University
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TERASHIMA Hanae
Graduate School of Life Sciences, Tohoku University
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IMAIZUMI Keiichiro
Graduate School of Life Sciences, Tohoku University
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