Synthesis of Novel α-C-Glycosylamino Acids and Reverse Regioselectivity in Larock's Heteroannulation for the Synthesis of the Indole Nucleus(Organic Chemistry)
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概要
- 論文の詳細を見る
An α-C-iodoethynylglucose derivative was coupled with an L-serine-derived zinc-copper reagent to give α-C-glucosylpropargyl glycine, which underwent palladium catalyzed-heteroannulation with o-iodoaniline to give not α-C-glucosyl-tryptophan but α-C-glucosyl-isotryptophan. This is the first observation of complete reverse regioselectivity to Larock's proposal.
- 社団法人日本農芸化学会の論文
- 2002-10-23
著者
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NISHIKAWA Toshio
Laboratory of Organic Chemistry, School of Bioagricultural Sciences, Nagoya University
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ISOBE Minoru
Laboratory of Organic Chemistry, School of Bioagricultural Sciences, Nagoya University
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Isobe Minoru
Laboratory Of Organic Chemistry Faculty Of Agriculture Nagoya University
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Wada Kyoko
Laboratory Of Organic Chemistry Graduate School Of Bioagricultural Sciences Nagoya University
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Nishikawa Toshio
Laboratory Of Organic Chemistry Graduate School Of Bioagricultural Sciences Nagoya University
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Isobe Minoru
Laboratory Of Organic Chemistry Bioagricultural Sciences Nagoya University
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