Magnetic Properties of Molecular Oxygen Adsorbed in Micro-Porous Metal-Organic Solids(Nanometer-Scale Magnets, Field-Induced Phase Transitions and Dynamics in Quantum Spin Systems)

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概要

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• The magnetic properties of O_2 adsorbed in nanochannels of porous metal-organic solids CPL-1 and CPL-p1 have been investigated by means of high-field magnetization process measurement. The contribution from adsorbed O_2 shows the metamagnetic-like behavior in both compounds. We propose "the field-induced rearrangement mechanism" as the explanation for the metamagnetic-like behavior. It is known for the O_2-O_2 dimer that the magnetic interaction depends strongly on the intermolecular distance and the orientation of molecular axes. It is considered naturally that the stable arrangement with saturated magnetic moment in the sufficient high field is different from the H-structure which is stable at zero field.

• 理論物理学刊行会の論文
• 2005-10-31

著者

• KINDO Koichi

  KYOKUGEN, Osaka University

• Kindo Koichi

  Kyokugen Osaka University

• Kobayashi Tatsuo

  Department of Material Physics, Faculty of Engineering Science, Osaka University

• MATSUO Akira

  KYOKUGEN, Osaka University

• Kitagawa S

  Graduate School Of Engineering Kyoto University

• SUZUKI Megumi

  KYOKUGEN, Osaka University

• KITAURA Ryo

  Graduate School of Engineering, Kyoto University

• MATSUDA Ryotaro

  Graduate School of Engineering, Kyoto University

• KITAGAWA Susumu

  Graduate School of Engineering, Kyoto University

• Kitaura Ryo

  Graduate School Of Engineering Kyoto University

• Matsuda Ryotaro

  Graduate School Of Engineering Kyoto University

• Suzuki Megumi

  Kyokugen Osaka University

• Matsuo Akira

  Kyokugen Osaka University

• Kobayashi Tatsuo

  Department Of Physics Faculty Of Science Okayama University

• Kobayashi Tatsuo

  Departmant Of Physics Kyoto University

• KOBAYASHI Tatsuo

  Department of Physics, Faculty of Science, Okayama University

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