X-Ray Diffraction Study of the Low Temperature Phase of Rubidium Cyanide
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概要
- 論文の詳細を見る
Crystal strvxcture of RbCN has been investigated on single crystals by X-ray precession pho-tographic rnethod at temperatures ranging frorn 300 to 85 K. At abottt 125 K, the crystal trans-forms frorn the cubic Nail-type phase into a low-ternperature phase in which a rnonoclinic and atriclinic forms coexist. Both the forrns ?tre related with the specific crystallographic orientationto the cubic lattice. The lattice constarxts of the monoclinic fortaa are av = 4.81(l), bu = 4.87(l),cu = 7.92(l) A, f3 : 122.7(l)' at 85 K, and the strvxcture is A-lc;tse-centered with the space groupA2/m. The lattice constants of the triclinic forxn are a-( : 9.79(l), 6T : 4.62(1), CT :: 4,88(1) A,a :: 121.1(l)', p : 119.4(l)', '7 : 90.0(l)' at 85K. Crystallographic relationships betweenthese forms and the cubic form are presented. The results are compared with the findings in therelated compound KCN.
- 社団法人日本物理学会の論文
- 1996-07-15
著者
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Iwasaki Hiroshi
Department of Pathology, Faculty of Medicine, Fukuoka University
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Iwasaki H
The Institute Of Scientific And Industrial Research Osaka University:basic Research Laboratory Semic
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Iwasaki Hiroshi
Department Of Anesthesiology And Critical Care Medicine Asahikawa Medical College
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Yoshimura Yasuo
Plasma Research Center University Of Tsukuba
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Iwasaki H
Department Of Photonics Faculty Of Science And Engineering Ritsumeikan University
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Iwasaki H
Department Of Botany Graduate School Of Science Kyoto University
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YOSHIMURA Yukio
Department of Physics,Faculty of Science and Engineering,Ritsumeikan University
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TSUDA Noritoshi
Department of Physics,Faculty of Science and Engineering,Ritsumaikan University
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SHINOHARA Seiichi
Department of Mathematics and Physics,Faculty of Science and Engineering,Ritsumeikan University
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Yoshimura Y
Kyoto Univ. Kyoto
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Shinohara Seiichi
Department Of Mathematics And Physics Faculty Of Science And Engineering Ritsumeikan University
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Tsuda Noritoshi
Department Of Physics Ritsumeikan University
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Tsuda N
Department Of Physics Faculty Of Science And Engineering Ritsumaikan University
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Yoshimura Yukio
Department Of Mathematics And Physics Faculty Of Science And Engineering Ritsumeikan University
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Iwasaki Hiroshi
Department of Photonics,Faculty of Science and Engineering,Ritsumeikan University
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