Simple Kinetic Theory of Thermal Diffusion in a Binary Hard Sphere Mixture

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概要

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• Based on the collision-theoretical results by Longuet-Higgins, Pople, and Valleaufor a binary hard sphere mixture, thermal diffusion is discussed at the most elemen-tary level to formulate it consistently with linear nonequilibrium thermodynamicswithout using the two-step logic outlined by the above authors. In accordance withthe previous proposition by the present authors (J. Phys. Soc. Jpn. 57 (1988) 3332),specific enthalpies transported and of transport play an important role in maintainingthe consistency under the Onsager reciprocal relation. Individual quantitiestransported and of transport are explicitly formulated, of which the quantities oftransport are subject to an analogue of the Gibbs-Duhem equation at constant temper-ature and pressure to validate an equation for the sum of the mechanical and ther-modynamic forces.

• 社団法人日本物理学会の論文
• 1989-07-15

著者

• Takeyama Naokata

  Department Of Applied Chemistry Faculty Of Science And Engineering Saga University

• Nakashima Kimie

  Department Of Applied Chemistry Faculty Of Science And Engineering Saga University

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• Steady-State Thermodynamics for Crossed Transport Phenomena of Heat and Matter
• Steady-State Thermodynamics and Thermopower of Metals
• Thermodynamic Background of the Limiting Law of Helfand and Kirkwood for the Ionic Heat of Transport
• Thermal Diffusion in a Lorentz Gas
• Thermodynamics of Thermal Diffusion in Aqueous Ionic Solutions
• The Heat of Transport of Water
• A Reduction Rule in Heats of Transfer for Aqueous 1-1 Electrolytes
• Basic Relationship for Thermal Quantities of Transport in Steady-State Thermodynamics
• On the Relation between Hydration Entropy and Surface Area of Ionic Stokes Spheres
• Entropy and Heat of Transport in Connection with Volume for Hydrophobic Ions
• Simple Kinetic Theory of Thermal Diffusion in a Binary Hard Sphere Mixture
• Thermal diffusion of prototropic ions in water.

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