Reformulation of Thermomolecular Pressure Effect toward Thermal Diffusion
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概要
- 論文の詳細を見る
In many standard monographs of nonequilibrium thermodynamics, there are incon-sistent parts of confusion in terminology as well as in notation, especially in the areaof thermal diffusion, between quantities of transport and transported. Such a situa-tion is corrected at an elementary level. As a result, the chemical potential of a diffus-ing species should be the "transported" Gibbs energy per mole. Based on this notion,the assumption of local equilibrium and the Gibbs equation can effectively and con-sistently be applied. Referring to a binary mixture, individual quantities of transportare discussed in harmony with "absolute" quantities introduced by de Groot andMazur, in connection with the relative quantities of transport in common use.
- 社団法人日本物理学会の論文
- 1988-10-15
著者
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Takeyama Naokata
Department Of Applied Chemistry Faculty Of Science And Engineering Saga University
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NAKASHIMA Kimie
Department of Applied Chemistry,Faculty of Science and Engineering,Saga University
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Nakashima Kimie
Department Of Applied Chemistry Faculty Of Science And Engineering Saga University
関連論文
- Relationship among Entropies,Volumes and Internal Pressures of Liquid Water and Aqueous Prototropic Ions
- Reformulation of Thermomolecular Pressure Effect toward Thermal Diffusion
- Steady-State Thermodynamics of Thermal Diffusion with Micelle Formation of Aqueous Ionic Surfactants
- Steady-State Thermodynamics for Crossed Transport Phenomena of Heat and Matter
- Steady-State Thermodynamics and Thermopower of Metals
- Thermodynamic Background of the Limiting Law of Helfand and Kirkwood for the Ionic Heat of Transport
- Thermal Diffusion in a Lorentz Gas
- Thermodynamics of Thermal Diffusion in Aqueous Ionic Solutions
- The Heat of Transport of Water
- A Reduction Rule in Heats of Transfer for Aqueous 1-1 Electrolytes
- Basic Relationship for Thermal Quantities of Transport in Steady-State Thermodynamics
- On the Relation between Hydration Entropy and Surface Area of Ionic Stokes Spheres
- Entropy and Heat of Transport in Connection with Volume for Hydrophobic Ions
- Simple Kinetic Theory of Thermal Diffusion in a Binary Hard Sphere Mixture
- Thermal diffusion of prototropic ions in water.