Magnetic and Transport Properties of Anatase TiO2 Codoped with Fe and Nb
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概要
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We have measured the magnetic and transport properties of FexNbyTi1-x-yO2-\delta ($x = 0.06$, $y = 0$, 0.1, 0.03) films deposited by pulsed laser deposition at various partial oxygen pressures ($P_{\text{O\scale70%$_{2}$}}$). The Fe and Nb codoped films have a carrier concentration of ${>}3\times 10^{20}$ cm-3, which is independent of $P_{\text{O\scale70%$_{2}$}}$ and far exceeds the critical carrier concentration for ferromagnetic ordering in Fe0.06Ti0.94O2-\delta ($1\times 10^{19}$ cm-3). Room-temperature ferromagnetism was observed only when deposition was conducted in reducing atmospheres (i.e., $P_{\text{O\scale70%$_{2}$}}\leq 1\times 10^{-6}$ Torr) for all the FexNbyTi1-x-yO2-\delta films, indicating that there is a critical oxygen vacancy density for the ferromagnetic transition.
- 2010-04-25
著者
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HIROSE Yasushi
Kanagawa Academy of Science and Technology (KAST)
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HASEGAWA Tetsuya
Kanagawa Academy of Science and Technology (KAST)
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Hirose Yasushi
Kanagawa Academy Of Science And Technology
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Shimada Toshihiro
Univ. Tokyo Tokyo Jpn
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Sakai Enju
Graduate School of Science, The University of Tokyo, Bunkyo, Tokyo 113-0033, Japan
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Chikamatsu Akira
Graduate School of Science, The University of Tokyo, Bunkyo, Tokyo 113-0033, Japan
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Hirose Yasushi
Graduate School of Science, The University of Tokyo, Bunkyo, Tokyo 113-0033, Japan
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Shimada Toshihiro
Graduate School of Science, The University of Tokyo, Bunkyo, Tokyo 113-0033, Japan
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Hasegawa Tetsuya
Graduate School of Science, The University of Tokyo, Bunkyo, Tokyo 113-0033, Japan
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Sakai Enju
Graduate School Of Science The University Of Tokyo
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Chikamatsu Akira
Graduate School Of Science The University Of Tokyo
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