Hydrolysis Constant and Coordination Geometry of Zirconium(IV)

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概要

• 論文の詳細を見る

• The solubility of zirconium was studied by comparing recent experimental data with predictions using an electrostatic hard sphere model. In the model, an antiprismatic structure was assumed for a mononuclear hydrolysis species of zirconium, and the formation of an oligomeric species such as Zr4(OH)88+ was considered by combining antiprismatic structure units, which was supported by the theoretical approach. By taking the known values of the solubility products, the hydrolysis constants of these mononuclear and polynuclear species were evaluated and were found to be consistent with the experimental solubility data of amorphous Zr(OH)4 and crystalline ZrO2.

• 社団法人 日本原子力学会の論文
• 2008-08-01

著者

• MORIYAMA Hirotake

  Research Reactor Institute, Kyoto University

• TAKAGI Ikuji

  Department of Nuclear Engineering, Kyoto University

• Takagi Ikuji

  Dep. Of Nuclear Engineering Kyoto Univ.

• Takagi I

  Kyoto Univ. Kyoto

• SASAKI Takayuki

  Department of Surgery, Shinshu University School of Medicine

• Takagi Ikuji

  Department Of Nuclear Engineering Kyoto University

• MORIYAMA Hirotake

  Department of Nuclear Engineering, Kyoto University

• Moriyama Hirotake

  Dep. Of Nuclear Engineering Kyoto Univ.

• Moriyama Hirotake

  Research Reactor Institute Kyoto University

• Moriyama Hirotake

  Department Of Nuclear Engineering Kyoto University

• KOBAYASHI Taishi

  Department of Nuclear Engineering, Kyoto University

• Kawasaki Toru

  Department Of Nuclear Engineering Kyoto University

• Kobayashi Taishi

  Department Of Nuclear Engineering Kyoto University

• Sasaki Takayuki

  Department Of Nuclear Engineering Kyoto University

• Sasaki Takayuki

  Department Of Biology Faculty Of Science Niigata University

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